Tool and high-speed steels

Tool steels are used for working, cutting, and forming metal components, moulding plastics, and casting dies for metals with lower melting points than steel. Accordingly, tool steels need high hardness and strength combined with good toughness over a broad temperature range.

The microstructure of all tool steels is based on a martensitic matrix. Molybdenum additions in tool steels increase both their hardness and wear resistance. By reducing the critical cooling rate for martensite transformation, molybdenum promotes the formation of an optimal martensitic matrix, even in massive and intricate moulds that cannot be cooled rapidly without distorting or cracking. Molybdenum also acts in conjunction with elements like chromium to produce substantial volumes of extremely hard and abrasion resistant carbides. Increasing physical demands on tool steels result in an increasing molybdenum content. Depending on their application, tool steels are classified into:

• Cold-work tool steels (Mo ≤1.8%)
• Hot-work tool steels (Mo ≤3.0%)
• Plastic mould steels (Mo ≤1.3%)
• High-speed tool steels (Mo ≥7%)

Cold-work steels

Cold-work tool steels are tool steels used for forming materials at room temperature or at slightly raised temperatures (~ 200°C). Specifically, tools for blanking metallic and non-metallic materials, including cold-forming tools, are manufactured from these steels.

Fundamentally, cold-work tool steels are high carbon steels (0.5-1.5%). The water-quenched W-grades are essentially high carbon plain carbon-manganese steels. Steel grades of the O series (oil-hardening), the A series (air-hardening), and the D series (high carbon-chromium) contain additional alloying elements that provide high hardenability and wear resistance as well as average toughness and heat softening resistance. 

The four major alloying elements in such tool steels are tungsten, chromium, vanadium, and molybdenum. These alloys increase the steels' hardenability and thus require a less severe quenching process with a lower risk of quench cracking and distortion. All four elements are strong carbide formers, also providing secondary hardening and tempering resistance.

Hot-work steels

Hot-work tool steels are tool steels used for the shaping of metals at elevated temperatures. Their principal areas of application include pressure die casting moulds, extrusion press tools for processing light alloys, and bosses and hammers for forging machines. The stresses encountered here are cyclical, often with abrupt temperature changes and recurring mechanical stresses at high temperatures. Hot-work steels must constantly endure tool temperatures above 200°C during use. To achieve optimum performance, hot-work tool steels require the following properties: 

• Good tempering properties
• Sufficient thermal stability
• High hot toughness
• High resistance to wear at elevated temperatures
• Good thermal fatigue resistance

Cycle times applied in plastic injection moulding, pressure die casting or press hardening (hot stamping) can be reduced considerably by increasing the tool steel’s thermal conductivity, which significantly raises productivity. Heat conductivity is influenced by several material parameters such as microstructure, defects, and alloying elements. 

Armco iron is nearly pure iron with a low defect density and high heat conductivity in the order of 70-80 W/mK. Compared to Armco iron, traditional hot-work steel such as H13 (1.2344) has much lower heat conductivity  in the range of only 20-30 W/mK. This reduced thermal conductivity is due to high lattice distortion and defect density of the (tempered) martensitic microstructure as well as to a substantial content of alloying elements. All these characteristics interact with phonons, electrons, and magnons as the “vehicles” of heat transport.

Since all hot-work steels have a defect-rich martensitic microstructure, the difference in optimizing heat conductivity lies in the alloying composition. When in solid solution, alloying elements can cause local lattice distortion (size misfit vs. iron), modify the electronic structure, and/or have influence on magnetism. Generally, heat conductivity is reduced as the alloy content increases. Looking at individual elements in a solute state, nickel, chromium, and silicon were found to negatively influence heat conductivity. The effects of vanadium and molybdenum appear less detrimental. After tempering, the amount of solute vanadium, chromium, and molybdenum decrease by carbide precipitation, which diminishes their negative effect on heat conductivity.

Plastic mould steels

Tools for processing plastics are mainly stressed by pressure and wear. According to the type of plastic, corrosive conditions can prevail in addition to stresses. The type of plastic and processing method define the key requirements in addition to those generally valid to hot-work steels:

• Economic machinability or cold-hobbing ability
• Smallest possible distortion upon heat treatment
• Good polishing behavior
• High compressive strength
• High wear resistance
• Sufficient corrosion resistance

High-speed steels

When tool steels contain a combination of more than 7% molybdenum, tungsten, and vanadium, and more than 0.60% carbon, they are referred to as high-speed steels. This term describes their ability to cut metals at “high speeds”. Until the 1950s, T-1 with 18% tungsten was the preferred machining steel. The development of controlled atmosphere heat treating furnaces then made it practical and cost effective to substitute part or all the tungsten with molybdenum.

Additions of 5-10% Mo effectively maximize the hardness and toughness of high-speed steels and maintain these properties at the high temperatures generated when cutting metals. Molybdenum provides another advantage: at high temperature, steels soften and become embrittled if the primary carbides of iron and chromium grow rapidly in size. Molybdenum, especially in combination with vanadium, minimizes this by causing the carbides to reform as tiny secondary carbides which are more stable at high temperatures. The largest use of high-speed steels is in the manufacture of various cutting tools: drills, milling cutters, gear cutters, saw blades, etc.

Additions of 5-10% molybdenum effectively maximize the hardness and toughness of high-speed steels and maintain these properties at the high temperatures generated when cutting metals. Molybdenum provides another advantage: steels soften and become embrittled at high temperature when the primary iron and chromium carbides grow rapidly in size. Molybdenum, especially in combination with vanadium, minimizes this softening by causing the carbides to reform as tiny secondary carbides that are more stable at high temperatures. 

The largest use of high-speed steels is in the manufacture of various cutting tools: drills, milling cutters, gear cutters, saw blades, etc.

The useful cutting characteristics of high-speed steel have been further extended by applying thin, ultra-hard coatings. These coatings reduce friction and increase wear resistance, thereby increasing cutting speed and tool life.

The exceptional high temperature wear properties of molybdenum-containing high-speed steels are also ideal for applications such as automobile valve inserts and cam-rings.