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Ferritic stainless steel

The ferritic family includes stainless steels with a broad range of corrosion resistance. The most widely used ferritic grade is Type 430, which has a corrosion resistance just below that of Type 304 austenitic stainless steel. At the lower end of corrosion resistance is Type 409, which is commonly used in automotive exhaust systems. The most corrosion resistant ferritic grades are the super ferritic stainless steels such as UNS S44660 and S44735, which have a corrosion resistance in many environments that is equal to that of the 6% Mo super austenitic grades. 

Ferritic grades are commonly used in appliances, tube applications and automotive exhaust systems. Because of their very low nickel content, ferritic stainless steels are less costly on a weight basis than the austenitic grades with a similar corrosion resistance. However, their lower toughness and less favourable fabrication properties limit their use. Ferritic grades that contain more than about 12% chromium are also susceptible to a loss of ductility due to alpha prime precipitation that occurs when heated to temperatures of 315 to 525°C (600 to 950°F). Because of this, the higher alloyed ferritic grades typically have a maximum service temperature of 315°C (600°F).

Chemical Composition* (weight%) and PREN of some common ferritic stainless steels**
Grade No. UNS EN No. C N Cr Ni Mo Cu Other PREN***
403 S40300 --- 0.15 1.0 0.5

11.5

13.0

0.60 11.5-12.5
405 S40500 --- 0.08 1.0 1.0

11.5

14.5

0.60 Al 0.10-0.30 11.5-13
409 S40910 1.4512 0.030 1.0 1.0

10.5

11.7

0.50 0.030

Ti 6x(C=N) min.,

0.50 max., Nb 0.17

10.5-12
430 S43000 1.4016 0.12 1.0 1.0

16.0

18.0

0.75 16-17
439 S43035 --- 0.03 1.0 1.0

17.0

19.0

0.50 0.030

Ti [0.2+4(C+N)] min.,

1.10 max., Al 0.15

17-18
434 S43400 1.4113 0.12 1.0 1.0

16.0

18.0

0.75

1.25

18.5-20
436 S43600 1.4526 0.12 1.0 1.0

16.0

18.0

0.75

1.25

Nb 5xC min.,

0.80 max.

18.5- 20
444 S44400 1.4521 0.025 1.0 1.0

17.5

19.5

1.0

1.75

2.50

0.035

(Ti+Nb) [0.20+4(C=N)]min.,

0.80 max.

23.5-25
XM-27 S44660 --- 0.030 1.0 1.0

25.0-

28.0

1.0

1.35

3.0

4.0

0.040

(Ti+Nb) 0.20-1.0,

Ti + Nb 6x(C=N) min

36-40
--- S44735 --- 0.030 1.0 1.0

28.0

30.0

1.0

3.6

4.2

0.045

(Ti+Nb) 0.20-1.00,

(Ti +Nb) 6x (C+N) min.

40-43

Notes:

* Taken from ASTM specifications for plate, sheet and strip when available or from company data sheets. For complete compositional requirements consult these sources.
** Chemistry maximum, unless range or minimum is indicated, EN chemistry does not correspond exactly to ASTM chemistry
*** Pitting Resistance Equivalent Number calculated from the expression PREN = %Cr + 3.3(%Mo + 0.5%W) and expected nominal chemical compositions for the grade